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General Reviews and New Techniques |
Fossil Fuels & Environmental Geochemistry (Postgraduate Institute): NRG, Drummond Building, University of Newcastle, Newcastle upon Tyne, NE1 7RU, UK
Petroleum reservoirs often contain compositionally heterogeneous petroleum, water and sometimes gas columns which can be interpreted in geologically useful ways. Kilometre-scale lateral compositional heterogeneities in fluid columns suggest petroleum emplacement directions, directions of water flow in biodegraded oilfields and the presence of major barriers to fluid flow within reservoirs. Vertical fluid column heterogeneities on a 10 m scale suggest that reservoirs are vertically compartmentalized. These data can be used as a tool in reservoir description and are thus relevant to many aspects of reservoir appraisal and development. The data supplement those generated by reservoir geologists and engineers, and can be obtained immediately after drilling, at reasonable cost.
Much recent work has focused on polar nitrogen (N) and oxygen (O) containing compounds such as quinolines, carbazoles and phenols. These compounds interact relatively strongly with water, rock minerals and each other, and may significantly influence the viscosity and pressure-volume-temperature (PVT) properties of petroleum, and also reservoir wettability. There are obvious links here between reservoir geochemistry and the more traditional disciplines of petroleum and reservoir engineering which we expect to be exploited in the coming years.
In the absence of phase changes during migration, the composition of reservoired oil reflects the expelled oil plus changes induced by adsorption, especially of polar compounds, onto solid phases or by partitioning into porewaters along secondary migration pathways. The extent of change, as measured by the relative abundances of selected compounds in reservoired oil and associated water, is potentially a direct measure of migration volume and thus of the relative amounts of water, oil and rock on a migration pathway. We present a simplified, equilibrium model which may allow one to assess migration volumes, and use n-hexane/benzene ratios of some North Sea oils to suggest that these oils have contacted fewer than one hundred volumes of water on their migration pathways. Future work should aim to quantify the interactions of migrating and reservoired petroleum with rock and water, and should yield a more quantitative assessment of both migration volumes and the controls of reservoir wettability.
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