Lyell Collection
Geological Society, London, Special Publications
Lyell Centre  |   Lyell Collection  |   Subscriptions   |   Geological Society  |   Email alerts  |   Online bookshop  |   Help

Keywords:
Author:
Advanced search>>
This Article
Right arrow Full Text (PDF)
Right arrow References
Right arrow Alert me when this article is cited
Right arrow Alert me if a correction is posted
Right arrow Citation Map
Services
Right arrow Email this article to a friend
Right arrow Similar articles in this journal
Right arrow Alert me to new issues of the journal
Right arrow Download to citation manager
Right arrow Request Permissions
Citing Articles
Right arrow Citing Articles via Google Scholar
Google Scholar
Right arrow Articles by Palacz, Z. A.
Right arrow Articles by Wolff, J. A.
Right arrow Search for Related Content
GeoRef
Right arrow GeoRef Citation
Geological Society, London, Special Publications; 1989; v. 42; p. 147-159;
DOI: 10.1144/GSL.SP.1989.042.01.10
© 1989 Geological Society of London

Strontium, neodymium and lead isotope characteristics of the Granadilla Pumice, Tenerife: a study of the causes of strontium isotope disequilibrium in felsic pyroclastic deposits

Z. A. Palacz & J. A. Wolff

Department of Earth Sciences, The Open University, Walton Hall, Milton Keynes MK7 6AA, Buckinghamshire, UK
VG Isotopes Ltd, Ion Path Road Three, Winsford, Cheshire CW7 3BX, UK
Department of Geology, University of Texas at Arlington, UTA Box 19049, Arlington, TX 76019, USA

The Granadilla Pumice deposit, the product of a single explosive eruption of phonolitic magma, exhibits stratigraphically systematic internal compositional variations interpreted as the result of fractionation of the observed phenocryst assemblage in the pre-eruptive magma body. Whole-rock 87Sr/86Sr data exhibit a consistent profile, with the most differentiated compositions having the most radiogenic strontium. The resultant 87Sr/86Sr versus 1/Sr mixing line has a positive slope, suggesting the addition of a relatively radiogenic strontium component to the existing strontium concentration profile. There is no significant systematic variation, however, in neodymium or lead isotopes. Separated alkali feldspar phenocrysts have 87Sr/86Sr values of 0.7031–0.7032, identical with Tenerife mafic magmas; the strontium isotopic variation is restricted to the complementary glasses. The more radiogenic component in the glasses is only partially removed by acid leaching and has a strontium isotope ratio of about 0.707, deduced from analysis of the leachant. Strong acid leaching, accompanied by up to 25% sample dissolution, results in greater, but not complete, loss of the more radiogenic component, with a good correlation between pre- and post-leaching glass isotopic compositions. These relationships cannot be easily explained by either post-eruptive alteration or contamination of the magma chamber with high-87Sr/86Sr country rock. The data are instead consistent with a model of interaction between vesiculating magma and hydrothermal fluids with high 87Sr/86Sr, immediately before and/or during explosive eruption, involving limited diffusion of strontium from the fluid into bubble walls before quenching of the magma to form glassy pumice. This process may be common during large explosive eruptions, and we suggest that whole-rock strontium isotope variations found in strontium-poor felsic pyroclastic deposits may not reflect purely magmatic processes, even though they closely mimic plausible magmatic variations.