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Geological Society, London, Special Publications; 1987; v. 29; p. 25-38;
DOI: 10.1144/GSL.SP.1987.029.01.03
© 1987 Geological Society of London

Part I Theory and Experimental

Pressure solution-deposition creep and associated tectonic differentiation in sedimentary rocks

J. P. Gratier

IRIGM, University of Grenoble 1 B.P. 68, 38402 Saint Martin d’Hères, France

Several models of pressure solution-deposition have been established by using various hypotheses: on the rate-limiting process of the deformation (kinetics of the solid/fluid reaction or rate of mass transfer); on the driving force for mass transfer (difference in normal stress or elastic, plastic or surface energies) and on the mechanism of mass transfer (diffusion or infiltration). These creep relations have been tested experimentally and in nature. In the last case the observations show that the pressure solution-deposition process is always associated with a chemical differentiation of the rocks when these rocks are initially composed of several minerals with various mobilities under stress. The aim of this paper is to discuss the development of this chemical (and mechanical) differentiation. The first part deals with the initiation and the development of the zone of dissolution (relation between stress and dissolution, effect of the initial heterogeneities, etc.) and of the zone of crystallization (effects of the nature of the rocks, processes of deposition, etc.). The second part deals with the development of chemical differentiation during the progressive deformation. The geometry and the equilibrium composition of the differentiated layer are fixed by various factors such as: the size of the dominant heterogeneities (initial or tectonically induced), the possibilities of mass transfer, the state of stress, and the nature of the solid and that of its solution. The wavelength of some stylolites could also be imposed by these various factors.





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