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New Approaches, Analytical and Geochemical Developments |
Petroleum/Geochemical Data, P.O. Box 671264, Dallas, TX 75367-1264, USA keithfmt{at}earthlink.net
Molar concentration profiles of reservoir fluids reveal accumulation history and alteration. Slope Factors (SF) define rates of exponential decrease in concentration of light n-alkanes (C3-nC5) and liquid pseudo-components (P10+) with increasing carbon number. Most petroleum fluids are substantially characterized by SF(C3-nC5) and SF(P10+), the former invariably being the greater. Specific paired values of SF(C3-nC5) and SF(P10+) are process-diagnostic. In oils, maturation, gas injection, evaporative fractionation and migration depletion involving loss of gas, are recognizable. SF data are interpreted in the light of PVT analyses representing oils (principally from western Canada) and gas-condensates (from numerous basins), also asphaltene pyrolysis experiments and equation of state calculations. Covariant increase of SF(C3-nC5) and SF(P10+) during maturation is demonstrated, but correlation is frequently destroyed by modification of the light ends by the admixture of allochthonous gas, increasing only SF(C3-nC5). Secondary gas-enrichment is a requisite process for the generation of gas-condensates by evaporative fractionation. Compositional criteria for the recognition of enrichment are provided for the first time, particularly attainment of a value of SF(C3-nC5) exceeding 1.69 (a tentative limit). Available data indicate that the process has occurred in a large proportion of oil accumulations, ranging from 23% of 30 reservoirs in the Jurassic Smackover Formation in Alabama, to 78% of 36 in the northern North Sea.
