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New Approaches, Analytical and Geochemical Developments |
School of Geology and Geophysics, University of Oklahoma, Norman, OK 73019, USA 001-405-325-3140 pphilp{at}ou.edu
Over the past 10 years, investigations into the characteristics of the high molecular weight hydrocarbon (HMWHC) fraction in crude oils and, to a lesser extent, source rock extracts have continued to reveal novel information concerning the distribution of hydrocarbons >C40. The major impetus for this work has come from the fact that HMWHCs can cause significant production problems in certain geographical regions and particularly deepwater frontier areas. Since these HMWHCs appear to be ubiquitous in crude oils, the primary questions that need to be addressed are: what are these compounds, where do they come from, and how do they affect physical properties of oils? Here, we review our work over the past decade and discuss the significance of these results and their potential application to reservoir and production problems involving paraffins and asphaltenes.
It was commonly believed for many years that only oils derived from source rocks containing higher plant source material would have a high paraffin content. However, it is now abundantly clear that oils derived from lacustrine and marine source rocks also contain relatively high concentrations of higher molecular weight hydrocarbons. In addition to developing methods for the qualitative and quantitative separation of HMWHCs from asphaltenes, progress has been made in identifying individual components of the high molecular weight fraction. This fraction is not a simple mixture of n-alkanes but a complex mixture of seven or eight homologous hydrocarbon series, each with significantly different physical properties. A knowledge of these structures is important in predicting crude oil properties such as cloud point and pour point. Series identified to date include alkylcyclopentanes, alkylcyclohexanes, alkylbenzenes and various branched hydrocarbons.
In summary, since the 1970s most of the geochemical research emphasis has been placed on compounds below C40. Whilst compounds above C40 may not have the same degree of structural specificity as the traditional biomarkers, the amount of information available from these compounds could be extremely beneficial in the long term, particularly for reservoir characterization and production purposes and other problems involving high molecular weight hydrocarbons.
