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1 Department of Earth Sciences, University of Keele, Keele ST5 5BG, UK p.a.floyd{at}esci.keele.ac.uk
2 Geological Institute, Wroclaw University, Wroclaw, Poland
During early Palaeozoic time the Cadomian basement of the northern margin of Gondwana underwent extensive rifting with the formation of various crustal blocks that eventually became separated by seaways. Attenuation of the continental lithosphere was accompanied by the emplacement of anatectic granites and extensive mafic-dominated bimodal magmatism, often featuring basalts with an ocean crust chemistry. Intrusive metabasites in deep crustal segments (associated with granitic orthogneisses) or extrusive submarine lavas at higher levels (associated with pelagic and carbonate basinal sediments) show a wide range of chemical characteristics dominated by variably enriched tholeiites. Most crustal blocks show the presence of three main chemical groups of metabasites: Low-Titholeiitic metabasalts, Main Series tholeiitic metabasalts and alkalic metabasalt series. They differ in the degree of incompatible element enrichment (depleted to highly enriched normalized patterns), in selected large ion lithophile (LIL) to high field strength element (HFSE) ratios, and abundances of HFSE and their ratios. Both the metatholeiite groups are characterized by a common enrichment of light REE-Th-Nb-Ta. High Th values (or Th/Ta ratios) and associated low
Nd values (especially in the Low-Ti tholeiitic metabasalts) reflect sediment contamination in the mantle source rather than at crustal levels, although this latter feature cannot be ruled out entirely. The range of chemical variation exhibited is a consequence of the melting of (a) a lithospheric source contaminated by a sediment component (which generated the Low-Ti tholeiites), and (b) a high-level asthenospheric mid-ocean ridge basalt (MORB)-type source that mixed with a plume component (which generated the range of enriched Main Series tholeiites and the alkali basalts). It is considered that a plume played an important role in the generation of both early granites and the enriched MORB-type compositions in the metabasites. Its significance for the initial fragmentation of Gondwana is unknown, but its presence may have facilitated deep continental crust melting and the fracturing into small crustal blocks. The early-mid-Jurassic plume-instigated break-up of the southern Gondwana supercontinent is considered to be a possible tectonic and chemical analogue for Early Palaeozoic Sudetic rifting and its magmatic products.
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